I dont think so.
I know it is a "chance" to happen thing since if you look in Pedstat.dat and change "Evade" to higher, they will do that more often and if u make it lower then they will use it less times.
I dont think that "Evade" works on the player tho.
Even tho, I think it can be used on the player and I believe it can be done via LUA action nodes and HxD (Not sure about HxD)